A Purdue University-led team developed a new material and manufacturing process that would make one way to use solar power — as heat energy — more efficient in generating electricity.
The innovation is an important step for putting solar heat-to-electricity generation in direct cost competition with fossil fuels, which generate more than 60 percent of electricity in the U.S.
“Storing solar energy as heat can already be cheaper than storing energy via batteries, so the next step is reducing the cost of generating electricity from the sun’s heat with the added benefit of zero greenhouse gas emissions,” said Kenneth Sandhage, Purdue’s Reilly Professor of Materials Engineering.
The research, which was done at Purdue in collaboration with the Georgia Institute of Technology, the University of Wisconsin-Madison and Oak Ridge National Laboratory, published in the journal Nature.
This work aligns with Purdue’s Giant Leaps celebration, acknowledging the university’s global advancements made for a sustainable economy and planet as part of Purdue’s 150th anniversary. This is one of the four themes of the yearlong celebration’s Ideas Festival, designed to showcase Purdue as an intellectual center solving real-world issues.
Solar power doesn’t only generate electricity via panels in farms or on rooftops. Another option is concentrated power plants that run on heat energy.
Concentrated solar power plants convert solar energy into electricity by using mirrors or lenses to concentrate a lot of light onto a small area, which generates heat that is transferred to a molten salt. Heat from the molten salt is then transferred to a “working” fluid, supercritical carbon dioxide, that expands and works to spin a turbine for generating electricity.
To make solar-powered electricity cheaper, the turbine engine would need to generate even more electricity for the same amount of heat, which means the engine needs to run hotter.
The problem is that heat exchangers, which transfer heat from the hot molten salt to the working fluid, are currently made of stainless steel or nickel-based alloys that get too soft at the desired higher temperatures and at the elevated pressure of supercritical carbon dioxide.
Inspired by the materials his group had previously combined to make “composite” materials that can handle high heat and pressure for applications like solid-fuel rocket nozzles, Sandhage worked with Asegun Henry, now at the Massachusetts Institute of Technology, to conceive of a similar composite for more robust heat exchangers.
Two materials showed promise together as a composite: The ceramic zirconium carbide, and the metal tungsten.
Purdue researchers created plates of the ceramic-metal composite. The plates host customizable channels for tailoring the exchange of heat, based on simulations of the channels conducted at Georgia Tech by Devesh Ranjan’s team.
Mechanical tests by Edgar Lara-Curzio’s team at Oak Ridge National Laboratory and corrosion tests by Mark Anderson’s team at Wisconsin-Madison helped show that this new composite material could be tailored to successfully withstand the higher temperature, high-pressure supercritical carbon dioxide needed for generating electricity more efficiently than today’s heat exchangers.
An economic analysis by Georgia Tech and Purdue researchers also showed that the scaled-up manufacturing of these heat exchangers could be conducted at comparable or lower cost than for stainless steel or nickel alloy-based ones.
“Ultimately, with continued development, this technology would allow for large-scale penetration of renewable solar energy into the electricity grid,” Sandhage said. “This would mean dramatic reductions in human-made carbon dioxide emissions from electricity production.”
M. Caccia, M. Tabandeh-Khorshid, G. Itskos, A. R. Strayer, A. S. Caldwell, S. Pidaparti, S. Singnisai, A. D. Rohskopf, A. M. Schroeder, D. Jarrahbashi, T. Kang, S. Sahoo, N. R. Kadasala, A. Marquez-Rossy, M. H. Anderson, E. Lara-Curzio, D. Ranjan, A. Henry, K. H. Sandhage. Ceramic–metal composites for heat exchangers in concentrated solar power plants. Nature, 2018; 562 (7727): 406 DOI: 10.1038/s41586-018-0593-1