Perovskite solar cells first appeared in 2009 with an efficiency of 3.8%. With the outstanding photovoltaic properties, perovskite solar cell has become a subject of vigorous research for sustainable power generation, with researchers around the world finding new ways to increase its energy conversion efficiency. It has currently established itself as one of the most promising solar cell materials.

Tandem solar cells made of silicon and metal halide perovskite compounds can convert a particularly large portion of the solar spectrum into electrical energy.

However, part of the light is reflected and is thus lost for purposes of energy conversion. Using nanostructures, the reflection can be reduced significantly ensuring that the solar cell captures more light. For example, pyramid-shaped microfeatures can be etched into silicon.

However, these features cause microscopic roughness in the silicon surface, making it no longer suitable as a substrate for deposition of extremely thin perovskite layers. This is because perovskites are normally deposited to a polished wafer using solution processing to form an extremely thin film, much thinner than the pyramidal features.

A rough-etched silicon surface layer, therefore, prevents the formation of a uniform conformal layer.

Efficiency improved from 23,4 % to 25.5 %

A team headed by HZB physicist Steve Albrecht has investigated an alternative approach of light management with textures in tandem solar cells. The team fabricated an efficient perovskite/silicon tandem device whose silicon layer was etched on the back-side.

The perovskite layer could be applied by spin-coating onto the smooth front-side of the silicon. The team afterward applied a polymer light management (LM) foil to the front-side of the device.

This enabled processing of a high-quality perovskite film on a flat surface, while still benefiting from the front-side texture. “In this way, we succeeded in considerably improving the efficiency of a monolithic perovskite-silicon heterojunction tandem cell from 23.4 % to 25.5 %,” says Marko Jošt, first author of the study and postdoctoral fellow in Albrecht’s team.

The numerical model shows the possibility for up to 32.5 %

In addition, Jošt and colleagues have developed a sophisticated numerical model for complex 3D features and their interaction with light. This enabled the team to calculate how different device designs with textures at various interfaces affect efficiency.

“Based on these complex simulations and empirical data, we believe that an efficiency of 32.5 % can realistically be achieved — if we succeed to incorporate high-quality perovskites with a band gap of 1.66 eV,” says Jošt.

Suitable for building integrated PV

And team leader Steve Albrecht adds: “Based on real weather data, we were able to calculate the energy yield over the course of a year — for the different cell designs and for three different locations.”

In addition, the simulations show that the LM foil on the front-side of the solar cell device is particularly advantageous under diffuse light irradiation, i.e. not only under perpendicularly incident light.

Tandem solar cells with the new LM foil could therefore also be suitable for incorporation in building-integrated photovoltaics (BIPV), opening up huge new areas for energy generation from large skyscraper facades.

Journal Reference:
Marko Jošt, Eike Köhnen, Anna Belen Morales-Vilches, Benjamin Lipovšek, Klaus Jäger, Bart Macco, Amran Al-Ashouri, Janez Krč, Lars Korte, Bernd Rech, Rutger Schlatmann, Marko Topič, Bernd Stannowski, Steve Albrecht. Textured interfaces in monolithic perovskite/silicon tandem solar cells: advanced light management for improved efficiency and energy yield. Energy & Environmental Science, 2018; DOI: 10.1039/C8EE02469C

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