Schematic image, showing the PCBM nanoribbons, comprising four PCBM molecules organized side by side. The grey balls represent the fullerene molecules (each consist of 60 carbon atoms), and the attached side arms are characteristic for PCBM molecules. The white “speed tracks” represent the ability for the nanoribbons to form electronic highways. Credit: Image courtesy of Umeå University

Physicists at Umeå University have, together with researchers at UC Berkeley, USA, developed a method to synthesise a unique and novel type of material which resembles a graphene nanoribbon but in molecular form. This material could be important for the further development of organic solar cells. The results have been published in the scientific journal ACS Nano.

The nanoribbons are composed of molecules with the chemical formula [6,6]-phenyl-C61-butyric acid methyl ester. For short it is denoted PCBM, and in practice it is a fullerene molecule (a football-shaped carbon molecule) with an attached side arm to increase its solubility. PCBM molecules are commonly used in organic solar cells since they have a very good ability to transport free electrons that are “generated” by solar light.

The researchers at Umeå University and UC Berkeley have now developed a method to arrange such molecules into thin, crystalline nanoribbons that are only four nanometres wide. The nanoribbons are grown in a solution process with quite high efficiency and all nanoribbons have a unique morphology with edges in a zigzag.

“It is a very intriguing material and the method is quite simple. The material resembles the more commonly known graphene nanoribbons, but in our material each carbon atom is ‘replaced’ by a molecule,” says Thomas Wågberg, associate professor at the Department of Physics, who has led the study.

The findings are interesting for several reasons; it is the first time that structures with so small dimensions have been produced with this type of molecule, and the dimensions of the nanoribbons suggest that they should be ideal as “electronic highways” in organic solar cells. An organic solar cell usually consists of two types of material, one that conducts the electrons and one that conducts the “holes” that are left behind when the electron gets an energy boost from the incoming solar light (you can see the transport of “hole” as an empty space in traffic moving backwards in a traffic queue moving forwards).

An electron conductor in organic solar cells should ideally form long pathways to the electrode but concurrently be thinner than 10-15 nanometres (approximately 10,000 times thinner than a normal hair). The newly developed PCBM nanoribbons fulfil all these requirements.

“Together with professor Ludvig Edman’s group at the Department of Physics at Umeå University, we are now investigating this material further as a potential component in organic solar cells in the hope of making such devices more efficient,” says Thomas Wågberg.

Our study is of course also interesting for fundamental reasons since it opens up possibilities to investigate important physical properties of molecular materials with nanoscale dimensions.

About nanoribbons

Carbon nanostructures exist in many different forms. Graphene is a single layer of carbon atoms, which can be “ripped” into nanoribbons under certain circumstances. Due to the decrease in dimensions along one direction, the graphene nanoribbons display many unique properties. Fullerenes on the other hand are football-shaped molecules also built up from carbon atoms, while PCBM are fullerene-like molecules with several interesting properties and an attached side arm to increase their solubility. In the current study the researchers have been able to construct nanoribbons comprising PCBM molecules instead of carbon atoms, so that the structure strongly resembles a graphene nanoribbon in molecular form.

Publication: Eduardo Gracia-Espino, Hamid Reza Barzegar, Tiva Sharifi, Aiming Yan, Alex Zettl, Thomas Wagberg. Fabrication of One Dimensional Zig-Zag [6,6]-Phenyl-C61-butyric Acid methyl ester Nanoribbons from Two Dimensional Nanosheets. ACS Nano, 2015
Story: Molecular nanoribbons as electronic highways | Umeå University — October 5, 2015

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